基于极课大数据的初中化学组卷及试卷评价

为了提高组卷质量,基于极课大数据建立初中化学校本题库,根据双向细目表,利用该系统的出卷功能进行组卷。采用SPSS软件对试卷难度、区分度、信度和效度进行综合分析和评价,可知基于极课所出试卷各项评价指标较优秀,符合考试要求,试卷质量高。     

Changes in the mechanical properties of compression moulded samples of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) degraded by Streptomyces omiyaensis SSM 5670

Streptomyces omiyaensis SSM 5670 was characterized by its ability to use compression moulded samples of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) as its sole carbon source. Biodegradation of PHBV in liquid mineral salts medium was investigated using scanning electron microscopy, gravimetric measurements, capillary viscometry, tensile testing and wide angle X-ray spectroscopy. The biodegradation of PHBV proceeds via surface erosion mechanism, resulting in the formation of pits by microbial attack. PHBV specimens lost about 45% of their original weight after 45 days of exposure. During the degradation process the elastic modulus reduces less than 10%. The formation of pores and microcracks initiated at the degraded pits determines the reduction of the elongation and stress at break. However, the true stress at break is practically independent of the degradation time. No significant changes of PHBV molecular weight or crystallinity were observed during biodegradation. The polymer chain cleavage occurred only at the specimen surface and does not discriminate between crystalline and amorphous states.     

A Bayesian approach to seafloor classification using multi-beam echo-sounder backscatter data

Seafloor classification using acoustic remote sensing techniques is an attractive approach due to its high-coverage capabilities and limited costs. The multi-beam echo-sounder (MBES) system provides high-resolution bathymetry and backscatter information with 100% coverage. In this paper, we present a seafloor classification method that employs the MBES backscatter data. The method uses the averaged backscatter data per beam. It, therefore, is independent on the quality of the MBES calibration. Also, its performance is insensitive to seafloor type variation along the MBES swathe and corrections for the angular dependence of the backscatter are not needed. The method accounts for the ping-to-ping variability of the backscatter intensity. It estimates both the number of seafloor types present in the survey area and the probability density function for the backscatter strength at a certain angle for each of the seafloor types. Application of the method to MBES backscatter data acquired in a well-known test area in the North Sea shows very good agreement with available ground truth. The method’s discriminatory performance for this area is demonstrated to be comparable to that of taking samples of the sediment. All seafloor types known to be present in the area are resolved for. Application of the method to the Stanton bank data set shows clearly separable areas that differ in seafloor composition.     

Organic light‐emitting device dark spot growth behavior analysis by diffusion reaction theory

Dark spot growth rate tracing experiments performed on an organic light‐emitting device show that moisture entering into the device is relatively properly fitted by Fick's diffusion equation in the substrate/indium tin oxide (ITO)/hole transport layer (HTL)/silver (Ag) structure. It is believed that the moisture is dissolved into the polymer layer, which results in a decrease in the diffusion coefficient in the device with the substrate/ITO/HTL/electroluminescent (EL) polymer/Ag structure. The diffusion and chemical reaction occurring in the cathode layer further decreases the diffusion coefficient in the device with the substrate/ITO/HTL/EL polymer/calcium/Ag structure. Useful parameters, such as diffusion and solubility constants, describing possible mechanisms happening during dark spot growth on organic light‐emitting diode devices are extracted. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 1697–1703, 2001     

Fracture of diamond coatings by high velocity sand erosion

This paper describes a study of the behaviour of diamond coatings when subjected to solid particle erosion from sand particles. The coatings were deposited by chemical vapour deposition (CVD) onto tungsten substrates and tested using a high velocity air–sand erosion test facility. The erosion tests were conducted using particle impact velocities of between 33 and 268 m/s. Examination of the eroded test specimens showed that the principal damage features were circumferential cracks and pin-holes. Comparison with Hertz impact theory revealed that the measured circumferential crack diameters were more than double the predicted Hertzian contact diameter. Moreover, a trend of increasing circumferential crack diameter with coating thickness, which is not predicted by Hertz, was found. Instead, the crack diameters showed good agreement with those predicted by the theory of stress wave reinforcement, which is more commonly associated with liquid impact damage of brittle materials. During impact, the bulk compression and shear waves are reflected at the rear surface of debonded regions of the coating to return to the front surface and reinforce the Rayleigh surface wave, which generates a tensile stress. Where this stress exceeds the local tensile strength of the coating, a ring of cracks surrounding the area of impact is created. The results from the present study therefore suggest that stress wave reflection is responsible for the formation of the cracks at locally debonded regions of the coating. This hypothesis was supported by images acquired using scanning acoustic microscopy, which showed that circumferential cracks and pin-holes were only found on areas of the coating that had become delaminated by multiple particle impacts during the erosion tests.     

气体钻水平井环空冲蚀能量分析

在建立水平井流动方程的基础上,通过气固两相流动基本数学模型的求解数值模拟不同工况条件下的气固混合物冲蚀能量,得出了冲蚀能量的变化规律。算例数值模拟显示:环空速度剖面主要由注气量大小决定,机械钻速的影响不大;相同注气量条件下,机械钻速降低与井下岩屑浓度等比例下降;注气量的增加能提高井眼净化程度,但不如降低机械钻速效果明显;环空总冲蚀能中气体冲蚀能量占绝对主要地位,岩屑冲蚀能量只占极小部分,在相同注气量条件下总冲蚀能量基本相同;岩屑冲蚀能量主要取决于机械钻速,机械钻速越大井底产生岩屑越多冲蚀能力越强,相同机械钻速条件下,较大注气量能提供较大岩屑运移速度,提高了岩屑冲蚀能量。     

Physical Properties and Erosion Behavior of Poly(trimethylene carbonate‐co‐ε‐caprolactone) Networks

Form‐stable resorbable networks are prepared by gamma irradiating trimethylene carbonate (TMC)‐ and ε‐caprolactone (CL)‐based (co)polymer films. To evaluate their suitability for biomedical applications, their physical properties and erosion behavior are investigated. Homopolymer and copolymer networks that are amorphous at room temperature are flexible and rubbery with elastic moduli ranging from 1.8 ± 0.3 to 5.2 ± 0.4 MPa and permanent set values as low as 0.9% strain. The elastic moduli of the semicrystalline networks are higher and range from 61 ± 3 to 484 ± 34 MPa. The erosion behavior of (co)polymer networks is investigated in vitro using macrophage cultures, and in vivo by subcutaneous implantation in rats. In macrophage cultures, as well as upon implantation, a surface erosion process is observed for the amorphous (co)polymer networks, while an abrupt decrease in the rate and a change in the nature of the erosion process are observed with increasing crystallinity. These resorbable and form‐stable networks with tuneable properties may find application in a broad range of biomedical applications.

     

Experiment investigation on effects of elastic modulus on cavitation erosion of silicone rubber

Research into cavitation phenomena in various fields shows that the elastic modulus of a boundary has a potential impact on cavitation erosion. To obtain the direct relationship between the elastic modulus of the boundary and cavitiation erosion, single-layer samples with different chemical composition and moduli, and double-layer samples with different elastic moduli and the same surface layer material, were prepared with silicone rubber. The results of cavitation experiments on single-layer samples, show that the coating chemical composition and mechanical properties together affect the cavitation morphology of the coating, and dominant factors vary with erosion stage. Through the cavitation test of double-layer samples, it was found that there is a positive correlation between the elastic modulus of the coating and the degree of cavitation. This study helps us to understand the relationship between coating elastic modulus and cavitation more directly, and provides theoretical and technical guidance for the application of anti-cavitation for elastic coating in engineering.     

Effect of pearlitic morphology with varying fineness on the cavitation erosion behavior of eutectoid rail steel

The present work discusses the effect of the pearlitic morphology with varying fineness on the cavitation erosion behavior of eutectoid rail steel. Cavitation erosion of three different types of the pearlitic steels (furnace-cooled, air-cooled, and forced-air-cooled) consisting of coarse, fine, and very fine microstructures were tested in 3.5% NaCl solution and compared with that of the as-received pearlitic rail steel. The variation in the mean depth of erosion (MDE) and mean depth erosion rate (MDER) with erosion time was analyzed. Furthermore, the cavitation erosion resistance of the as-received, the air-cooled, and the forced-air-cooled was found to be 1.03, 1.51, and 2.14 times better than the furnace-cooled pearlitic steel, respectively. It was concluded that the cavitation erosion resistance of the pearlitic steel increased with the increase in the fineness of the microstructure.     

含气量对激光空泡在刚性壁面空蚀的影响

采用强脉冲激光器设计液体环境下刚性壁面空蚀实验平台,改变液体中含气量,利用高速相机观察不同含气量条件下激光空泡在壁面附近的脉动过程,并对刚性壁面造成的空蚀结果进行了观测。实验研究发现,随着液体中相对空气含量的提高,激光空泡脉动的最大尺寸增大,空泡的膨胀运动变剧烈,溃灭运动速度降低,空泡的溃灭强度降低,从而影响到溃灭冲击波和壁面微射流对刚性壁面的冲击速度,减弱了壁面空蚀,而液体中含气量的提高能够降低激光空泡对刚性壁面的空蚀程度。